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111.
U–Pb zircon geochronology, Sr–Nd isotope and bulk-rock geochemistry have been applied to meta-igneous and meta-sedimentary rocks from high-pressure metamorphic mélanges exposed on the Cycladic islands of Tinos, Syros and Andros. Ion microprobe (SHRIMP) U–Pb zircon dating of 7 samples representing meta-igneous blocks (Tinos), a blackwall zone (Tinos) and chlorite–talc schists from block-matrix contacts (Syros and Tinos) yielded Cretaceous ages of c. 80 Ma. Many of the criteria commonly used to distinguish between magmatic or metamorphic zircon genesis (internal structure, Th/U ratio, REE characteristics, Ti-in zircon thermometry, enclosed mineral phases) do not provide unambiguous constraints for the mode of formation. However, a magmatic origin for Cretaceous zircon of meta-gabbros and eclogites is considered likely. Supporting evidence for a previously suggested metamorphic origin for c. 80 Ma zircon in eclogite has not been found. Zircon of the same age occurring in chlorite–talc schists is presumably related to non-magmatic processes. Well-defined Cretaceous age groups clustering at c. 79 Ma also occur in the detrital zircon populations of 2 quartz mica schists representing the mélange matrix on Tinos, and suggest a much later time for sediment accumulation than previously assumed. The importance of c. 57 Ma zircon ages remains unclear, but may record either HP metamorphic processes or a post-57 Ma depositional age. The youngest age group in a third quartz mica schist from Tinos, collected outside the main mélange occurrences, clusters at c. 226–238 Ma. In all clastic metasediments from Tinos, most data points plot along the concordia between c. 300 and 900 Ma; single data points indicate concordant ages of c. 2.5 Ga, 2.3 Ga and 1 Ga, respectively. The youngest 206Pb/238U age group that has been recognized in a felsic paragneiss from Andros indicates an age of 163.1 ± 3.9 Ma, and mostly represents overgrowths around zircon with ages in the range from ~ 272 to ~ 289 Ma. Single data points of other inherited cores provided 206Pb/238U ages of c. 630 and c. 930 Ma. Meta-gabbros from Tinos show a large compositional variability and were found at 4 locations, each with distinct compositional characteristics, suggesting different crystallization histories, different sources and/or significant post-magmatic disturbance. The geochemistry of mélange blocks and the identical U–Pb zircon ages suggest that the block-matrix associations on Tinos and Syros can be grouped together. On a broader regional scale, there seem to be similarities between some meta-igneous rocks from Tinos and Evvia. Field relationships indicate that the mélanges occurring in southern Andros and northern Tinos can be correlated, but supporting geochemical and/or geochronological evidence for this interpretation could not be established. Previously published Jurassic ages for mafic and felsic mélange blocks from Andros suggest a genetic relationship to the ophiolite occurrences exposed in the larger Balkan region. A similar regional correlation is also considered likely for the Cretaceous meta-gabbros from Tinos and Syros, but cannot be documented with certainty.  相似文献   
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113.
We describe the design, optimization, electrical and optical tests of Microwave Kinetic Inductance Detectors (MKIDs) for the mm-wave range. Our detectors are based on a novel resonator design, and are suitable for ground-based astronomical observations in the 143 GHz atmospheric window. The measured optical Noise Equivalent Power (NEP) at 0.3 K is $\sim 10^{-16}~\text{W}/\sqrt{\rm Hz}$ under a 300 K background load. This is equivalent or better than the performance of the best current bolometric detectors for the 140 GHz atmospheric window, limited by atmospheric noise in the best available sites. We also describe which improvements can be introduced to reduce the NEP of our detector, for lower background applications (narrow band or space-based).  相似文献   
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115.
A mathematical model to calculate soil heat flux in three steps is presented. In the first, an hourly air temperature based on the average daily temperature, using Fourier series coefficients is estimated. The estimated hourly air temperature constitutes an input variable for the second step of the model. In the second step, heat transfer principles, using the thermal properties of the soil in order to obtain a soil temperature profile in a 1-m-depth soil stratum, is applied. Finally, the results of the second stage are used to numerically calculate hourly heat flux in the soil. Correlation coefficients between observed and calculated hourly temperature values over the three summer months were 0.98, 0.97 and 0.96. Correlation coefficient for the entire study period between observed and estimated soil heat-flux values was 0.92 with a mean square error of 19.8 W m–2.  相似文献   
116.
Spectral properties of volcanic materials in the optical region (350–2500 nm) of the electromagnetic spectrum are analyzed. The goal is to characterize air-fall deposits, recent lava flows, and old lava flows based on their spectral reflectance properties and on the textural characteristics (grain size) of pyroclastic deposits at an active basaltic volcano. Data were acquired during a spectroradiometric field survey at Mt. Etna (Italy) in summer 2003 and combined with hyperspectral satellite (Hyperion) and airborne LiDAR (Light Detection and Ranging) data. In addition, air-fall deposits produced by the highly explosive 2002–2003 eruption have been sampled and spectrally characterized at different distances from the new vents. The spectral analysis shows that air-fall deposits are characterized by low reflectance values besides variations in grain size. This distinguishes them from other surface materials. Old lava flows show highest reflectance values due to weathering and vegetation cover. The spectral data set derived from the field survey has been compared to corrected satellite hyperspectral data in order to investigate the Hyperion capabilities to differentiate the surface cover using the reflectance properties. This has allowed us to identify the 2002–2003 air-fall deposits in a thematic image just few months after their emplacement. Moreover, the observed differences in the field spectra of volcanic surfaces have been compared with differences in the signal intensity detected by airborne LiDAR survey showing the possibility to include information on the texture of volcanic surfaces at Mt. Etna. The approach presented here may be particularly useful for remote and inaccessible volcanic areas and also represents a potentially powerful tool for the exploration of extraterrestrial volcanic surfaces.  相似文献   
117.
Middle Ordovician acritarchs, including enigmatic, spore-like microfossils, are recorded from the Labrado and Capillas formations, of the Sierras Subandinas (Capillas River Section, Sierra de Zapla), northwestern Argentina. The Sierras Subandinas represent the outermost exposures of the Central Andean Basin that display an alternation of shallow-marine deltaic systems and estuarine environments, where relative sea-level fluctuations are frequent. The scarcity of fossils in the section, due to the marginal marine settings and frequent subaerial exposures, hinders the biostratigraphic constraining of these sedimentary successions. Based on the palynological assemblages, a probably Dapingian age is interpreted for the upper Lagunilla Member of the Labrado Formation, whereas the lower part of the Capillas Formation is assigned to the Darriwilian. Acritarchs from the lower part of the Capillas Formation indicate clear affinities with the “peri-Gondwana province”. However the lack of Frankea, a marker taxa for the Middle Ordovician, could be related either to the intermediate paleolatitudinal position of the Central Andean Basin or to local paleoenvironmental conditions. The facies analysis and the distribution of palynomorph assemblages throughout the studied section, suggest that organic-walled microfossils are influenced by local paleoenvironmental conditions. A probable non-marine origin is proposed for the spore-like microfossils co-occurring within the acritarch assemblages.  相似文献   
118.
Hydrolysis constants of dimethyltin(IV) cation, in different salt solutions (CaCl2: 0.15 I 0.90; MgCl2: 0.30 I 0.60; NaCl-–NaClO4, NaCl-–NaNO3 mixtures: I = 3; NaCl-–Na2SO4 mixtures: I = 1 mol dm-3) were determined by potentiometric ([H+]-glass electrode) measurements. These data, together with previous data (De Stefano et al., 1996b) were interpreted in terms of DHT (Debye–Hückel type) and Pitzer equations. The mixed electrolyte solution results also allowed us to obtain and parameters for the Pitzer equation. Calorimetric measurements were made at different ionic strengths in order to find the temperature dependence of hydrolysis constants and of the relative interaction parameters. The body of results allows us to determine the speciation of natural waters in a wide range of ionic strengths and temperatures.  相似文献   
119.
ABSTRACT

Levees are the most common structural solution to prevent flooding, reduce damage and generate benefits through more investment/economic activity in floodplain areas. While being relatively easy to build, levee effectiveness can be compromised by poor design and substandard construction methods and maintenance, thus increasing failure probability. Further, levees might increase societal vulnerability by instilling a sense of safety, the so-called “levee effect”. To cope with these phenomena, we develop a risk-based framework that quantifies residual risk under levee breaching and the levee effect, by disentangling its structural, dynamic and anthropic components, thus contributing to a better understanding of the phenomena at different spatial scales and the definition of flood risk policies. Through an illustrative example, we show how residual risk might become larger than under natural conditions, as function of the scale of interest, e.g. an area, a line at a given distance from the river, or a point within the floodplain.  相似文献   
120.
The structural phase transition in titanite is correlated with a strong temperature dependence of Raman scattering cross sections and, to a somewhat lesser extent, with shifts of the phonon frequencies. Their quantitative temperature evolution in the low-symmetry phase (P21/a) is compatible with a nearly 2D Ising behaviour with β≈0.12 and T c = 497 K. At temperatures above 860 K, the phonon signals agree with A 2/a symmetry but not in the temperature interval between 497 K and 860 K. In this temperature range new structural states give rise to additional phonon signals. A model based on mobile APBs between slabs of P21/a material, first proposed by van Heurck et al. (1991), is in qualitative agreement with our experimental observations.  相似文献   
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